Here we are booted with a base image:
And a quick cat of the disk:
So what was it in the end?
Firstly, I need to sort out better leads for my bench PSUs, they are very lossy and everything was unstable until I could get that sorted.
Secondly, I learned that holding down 'BREAK' on boot lets you skip the HDD and boot to BASIC, from where I am able to run a test routine from ROM. Ian, who is the seller of the told me about that, and it reported FreHD had failed.
With that in mind I flashed the PIC with v2.13 of the firmware rather than 2.14 as Ian advised I do that.
Then I found an completely unconnected post on PCBWay where somebody had uploaded the PCB, but pointed out a problem where a transistor, Q1, needed to be removed and pins 1&3 bridged, so I did that and lo and behold it works!!!
However, I don't want to get to ahead of myself, but this is a good place to start and requires more testing, but it's looking good

